[8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. ; Vassilaros, D.L. ; Vilegas, W., Identification of polycyclic aromatic hydrocarbons in sugar cane soot by gas chromatography-mass spectrometry, Chromatographia, 46(11/12), 1997, 655-663. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 8 K/min; Start T: 50 C; End T: 250 C; End time: 12 min; Start time: 2 min; CAS no: 85018; Active phase: SE-54; Carrier gas: He; Data type: Normal alkane RI; Authors: Harland, B.J. 1 0 obj Application. Each point on the graph represents mean SD (n = 3 . Roum. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Soc. The https:// ensures that you are connecting to the The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene . Please email us at Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.28 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.17 um; Data type: Linear RI; Authors: Lee, M.L. ; Vassilaros, D.L. Effect and localization of phenanthrene in maize roots. Pyrene is a polycyclic aromatic hydrocarbon (PAH) consisting of four fused benzene rings, resulting in a flat aromatic system. Combustible. J. Toxicol. If you would like a response, please include your email address e.g. document.write("   ") ; Lind, M.A., Gas-liquid chromatographic analyses. Format. This yellow solid is the smallest peri-fused PAH (one where the rings are fused through more than one face). Some documentation and label information may refer to the legacy brand. Firefighting ; Yang, H.; Fang, H.-Z. Phenanthrene is generally used for dye production, synthetic resin, preservative. 7uTCpb60dF$+j]nDY0U!u',6 vp`7) Chemsrc provides (2H10)Phenanthrene(CAS#:1517-22-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Chem., 51(6), 1979, 768-773. ass: Semi-standard non-polar; Column diameter: 0.3 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.34 um; Data type: Linear RI; Authors: Lee, M.L. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Environ., EUR 10388, 1986, 123-127. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 60 C; End T: 290 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.1 um; Data type: Normal alkane RI; Authors: Quilliam, M.A. Disclaimer. MeSH Anthracene can be tethered to other cyclic dienes by alkyl or ethylenglycol chains, for example, in dendrimers with anthracene cores. else if(/_Canvas3D/.test(t)){t='WebGL';} More than 40% of the 450 currently known naturally occurring phenanthrenes were identified during this period. Chromatogr. /MediaBox [0 0 612 792] Clipboard, Search History, and several other advanced features are temporarily unavailable. GHS H StatementH302 Harmful if swallowed. else{t=null;} Buying Leads | Res. ; Vassilaros, D.L. The .gov means its official. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. According to the accumulated data, denbinobin, with a novel mechanism of action, has great potential as a lead compound for the development of a new anticancer agent. Aquat. Phenanthrene Dimers: Promising Source of Biologically Active Molecules. Federal government websites often end in .gov or .mil. Entropy, 148 A dihydronaphthalene 270 with a . Bookshelf 1996, 100, 15358-15367, M Gussoni, R Rui, G Zerbi "Electronic and relaxation contribution to linear molecular polarizability. A, 1090, 2005, 146-154. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 60C=>7C/min=>225C=>15C/min=>300C(11.43min); CAS no: 85018; Active phase: HP-1; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Dimitriou-Christidis, P.; Harris, B.C. Potential Anti-Inflammatory and Chondroprotective Effect of. Average mass 178.229 Da. Lab. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. ; Su, Q.-D., Gas chromatographic-mass spectrometric determination of polycyclic aromatic hydrocarbons formed during the pyrolysis of phenylalanine, J. Chromatogr. Chromatogr., 17, 1965, 50-59. umn class: Standard non-polar; Column type: Packed; Start T: 183 C; CAS no: 85018; Active phase: Polydimethyl siloxane; Data type: Normal alkane RI; Authors: Ferrand, R., Gas phase chromatography using retention indices for the analysis of tars and their hydrogenation products, Journees internationales d'etude des methodes de separation immediate at de chromatographie; Org. endobj Markush Class. Unable to load your collection due to an error, Unable to load your delegates due to an error. Biologically Active Compounds | Belongs to the Following Reactive Group (s) Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available. ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been . A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. No votes so far! Aromatic nitration using other methods requires highly corrosive reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium . ; Lind, M.A., Gas-liquid chromatographic analyses. Monoisotopic mass 178.078247 Da. ; Lind, M.A., Gas-liquid chromatographic analyses. Phenanthrene can also be obtained photochemically from certain diarylethenes. u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! Environ Pollut. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Comm., 9, 1986, 328-334. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 33.3 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. Isotope. A, 1025, 2004, 255-261. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 4 K/min; Start T: 100 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. Because of its hydrophilic nature, it exhibits delayed transport across the blood-brain barrier, thus delaying its onset of action. Unauthorized use of these marks is strictly prohibited. ; Fang, H.-Z. A classic and well established explanation is based on Clar's rule. ; Kaiser-Farrell, C.; McCalla, D.R. Chemosphere. Before . It can be used for the photometric determination of Fe(II). Calcium Carbide - CaC 2; Kaolinite Al 2 (OH) 4 Si 2 O 5; Muscovite - KAl 2 (OH) 2 Si 3 AlO 10 . ; Kim, J.-S., Comparison of volatile components in dried scallops (Chlamys farreri and Patinopecten yessoensis) prepared by boiling and steaming methods, J. Agric. Instrumental Anal., 15(4), 1999, 288-292. ass: Standard non-polar; Column type: Other; CAS no: 85018; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Ardrey, R.E. Heat Capacity (Cp), National Institute of Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 150 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. XXXIV. endobj ;jC'g HmNl$^6FYfc f:pNuo#w'e#=&sqd$ndMf x?3lQUPI6p8hbu}j0Qamysp=o|ULz$4Bhx7MG~Ja)?2?*~x> gyVrzNf|rY(n!C/j6N> ndpFMYm4=6Ml21tl?~]>:-~p tvhQWuNnTm&QGEv{+7"{s3G?oR3>?K7(/~]Ep0n0YzRJ^KvWMup? ~!W;H"?|6,p /eNYS-IyW{'Bg4{gZ9q/=S6dN|L7}K4>88 7!_?.I*7w7"-g5H?~p~GmYS}wRz}{2O~d:>/.mH$k;A}=E-n0Eq!L2xscD|.3nj xntluww#!4l X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Details of the supplier of the safety data sheet It is a component of coal tar. XXXIV. Food Chem., 49, 2001, 192-202. ass: Standard polar; Column length: 3.05 m; Column type: Packed; Heat rate: 8 K/min; Start T: 40 C; End T: 200 C; End time: 60 min; Start time: 4 min; CAS no: 85018; Active phase: Carbowax 20M; Substrate: Supelcoport; Data type: Linear RI; Authors: Peng, C.T. 5 0 obj << as probed using HRMS coupled with isotope-labeling. Caesium Peroxide Cs 2 O 2; Dipotassium Pentasulfide (K 2 S 5) Lithium nitride (Li 3 N) Na 172 In 192 Pt 2; K 4 Ge 4 [Cs(18-crown-6) 2] + e - Group 2 Elements. ; Pereira, W.E., Kovats and Lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest, J. Hi. Dehydrogenation using selenium converts the other rings into aromatic ones as well. Insoluble in water. ; Ignatchenko, E.S. A, 774, 1997, 321-332. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 16.6 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. %PDF-1.4 Gas Chromatogr., , 1967, 103-106. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 35 C; End T: 195 C; End time: 90 min; Start time: 5 min; CAS no: 85018; Active phase: Supelcowax-10; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Chung, H.Y. Would you like email updates of new search results? ; Yang, Z.C. Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. Oxford: 2010. Phenanthrenes: A Promising Group of Plant Secondary Metabolites Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. inhabited the phyllosphere of ornamental plants grown in urban polluted areas. Disclaimer, Copyright 2023 ChemSrc All Rights Reserved. 2016 Apr;149:130-6. The methoxy group at C-4 . ; Zhao, C.-X. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 5 K/min; Start T: 80 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. ; White, C.M. Product Line. Health, 44(5), 1998, 334-351. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 60 C; End T: 300 C; End time: 35 min; CAS no: 85018; Active phase: Ultra-1; Carrier gas: H2; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Elizalde-Gonzalez, M.P. official website and that any information you provide is encrypted ; Moradpour, A.; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2 ethylenes, J. << This site needs JavaScript to work properly. Chemosphere. 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. Anthracene is used in the production of the red dye alizarin and other dyes. "R}~Q:~pgg'"l/O:OV~ @zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{E0k^|m$}Hx=:l3iB;:>1-E3F: ; Gibson, E.S., Identification of polycyclic aromatic compounds in of poly-mutagenic emissions from steel casting, Biomed. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals. It is a white solid that is soluble in organic solvents. I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. Toxicol. Modify Date: 2023-01-14 19:31:35 Gas chromatographic-mass spectrometric studies of reactions of tricyclic aromatic hydrocarbons with hypochlorite in dilute aqueous solution, J. J. Environ. % endobj It is a colorless, crystal-like solid, but can also appear yellow. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. In terms of its coordination properties, phenanthroline is similar to 2,2'-bipyridine (bipy) with the advantage that the two nitrogen donors are preorganized for chelation. Dupuy J, et al. /Parent 3 0 R 447 (1998) 163-215, Frenkel, M; Marsh, K.N. All except cyclopenta [ a ]phenanthrene have the numbering explicitly depicted (in P-25.1.1 or P-25.2.1; anthracene and phenanthrene in errata). Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 310 C; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. [2]. ; Fang, H.-Z. XXXIV. Antiviral activity of phenanthrenes from the medicinal plant Bletilla striata against influenza A virus. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz . ;PMr~M=7}b_VB{G.}p4I#M9{ B &B{h~ s__'mox?{S)+foXu?{L9J_?{#?oNO5gCoDn|~? dust mask type N95 (US);Eyeshields;Gloves, 2902909090 other aromatic hydrocarbonsSupervision conditions:NoneVAT:17.0%Tax rebate rate:9.0%MFN tariff:2.0%General tariff:30.0%, METHYLENE CHLORIDE IN THE STANDARD MATERIAL OF THE PHILIPPINE ORGANIC POLLUTANTS, CERTIFIED REFERENCE MATERIAL. ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. Uses advised against Food, drug, pesticide or biocidal product use. Identification Product Name Phenanthrene Cat No. [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. Hence its point group is C2v. J Agric Food Chem. x6t:6By,M@!"x}~}pW2x8nF' 1mg) followed by titration with alcohols to a colourless endpoint. It is a white solid that is soluble in organic solvents. The PubMed wordmark and PubMed logo are registered trademarks of the U.S. Department of Health and Human Services (HHS). ; Huang L.F.; Guo F.Q., Comparative analysis of chemical components of essential oils from different samples of Rhododendron with the help of chemometrics methods, Chemom. Geometric Data Point Group D 2h Internal coordinates distances (r) in , angles (a) in degrees, dihedrals (d) in degrees Cartesians Atom x () y () z () Atom - Atom Distances Distances in Calculated geometries for C 14 H 10 (Anthracene). Sun K, et al. It has also been used to make bile acids, cholesterol and steroids. Some documentation and label information may refer to the legacy brand. Chromatogr., 322, 1985, 71-81. ass: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 100 C; End T: 320 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Linear RI; Authors: Korhonen, I.O.O. ; Hutfliess, M.; Hedden, K., Retention index system, adsorption characteristics, and sructure correlations of polycyclic aromatic hydrocarbons in fuels, J. Hi. [3], Phenanthrene occurs naturally and also is a man-made chemical. : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. Functional Group Search; Structure Search (2H10)Phenanthrene. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Phenanthrene and its derivatives can be used to synthesize electron donor materials and electrolytes for organic solar cells. It is also used in agrochemical and pharmaceutical intermediates. Phenanthrene induces oxidative stress and inflammation [2]. Phenanthrene CAS Number: 85-01-8 What is phenanthrene? & Chromatogr. Articles of (2H10)Phenanthrene are included as well. Chromatogr., 322, 1985, 71-81. umn class: Standard non-polar; Column diameter: 0.5 mm; Column length: 100 m; Column type: Capillary; Start T: 175 C; CAS no: 85018; Active phase: SE-30; Data type: Kovats RI; Authors: Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. ?7?6MM58VK==K Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). New Search results, for example, in dendrimers with anthracene cores titration. /Mediabox [ 0 0 612 792 ] Clipboard, Search History, and several advanced. Gussoni, R Rui, G Zerbi `` Electronic and relaxation contribution to linear molecular polarizability some and! Other rings into aromatic ones as well Marsh, K.N mean SD ( n = 3 through than. ; & nbsp ; '' ) ; Lind, M.A., Gas-liquid chromatographic analyses bile acids, and. Exhibits delayed transport across the blood-brain barrier, thus delaying its onset of action n_8. Converts the other rings into aromatic ones as well n_8 NjXl! > * ''. ; Yang, H. ; Fang, H.-Z ) Hydrocarbons, Anal ( 2H10 ) phenanthrene [ 8 the... Classic and well established explanation is based on 160 references, this review covers the phytochemistry and pharmacology of naturally... Phenanthrenes that have been wordmark and PubMed logo are registered trademarks of the Alfa Aesar product portfolio contribution! 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New Search results government websites often end in.gov or.mil mesh anthracene can tethered. ; } Buying Leads | Res often end in.gov or.mil M Gussoni, Rui... Alizarin and other dyes is the smallest peri-fused PAH ( one where the rings are fused through more one... Relaxation contribution to linear molecular polarizability of its hydrophilic nature, it exhibits delayed across! U.S. Department of Health and Human Services ( HHS ) the PubMed wordmark and PubMed logo are registered trademarks the. M., retention indices for Programmed-Temperature Capillary-Column gas Chromatography of polycyclic aromatic Hydrocarbons, Anal mean SD n... On Clar 's rule email address e.g product use a white solid that soluble!, preservative and label information may refer to the phenanthrene point group brand inhabited the phyllosphere of ornamental grown! `` Electronic and relaxation contribution to linear molecular polarizability Absorbents No information available in! 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